Title

Adsorptive removal of antibiotic sulfonamide by UiO-66 and ZIF-67 for wastewater treatment

Document Type

Journal Article

Publisher

Elsevier

School

School of Engineering

RAS ID

24657

Comments

Original article published as : Azhar, M. R., Abid, H. R., Periasamy, V., Sun, H., Tade, M. O., & Wang, S. (2017). Adsorptive removal of antibiotic sulfonamide by UiO-66 and ZIF-67 for wastewater treatment. Journal of Colloid and Interface Science, 500, 88-95. Original article available here

Abstract

Adsorptive removal of a toxic sulfonamide antibiotic, sulfachloropyradazine (SCP), from aqueous solution was studied on several metal organic frameworks, UiO-66 and ZIF-67, for the first time. UiO-66 exhibited a much higher adsorption capacity than ZIF-67, fast kinetics, and easy regeneration for reuse, demonstrating as a promising adsorbent in wastewater treatment processes. The batch adsorption shows an adsorption capacity of SCP at 417 mg/g on UiO-66. The kinetic adsorption of SCP on UiO-66 reached equilibrium just in 10 min and the kinetics fits accurately with a pseudo 2nd order model. A plausible mechanism was proposed based on pH effect, pKa value of the adsorbate and Zeta potential of UiO-66. The high adsorption is mainly contributed to hydrophobicity and π-π interactions along with electrostatic interactions. Thermodynamic studies show the spontaneous adsorption and exothermic process. The easy regeneration and high adsorption capacity confirms structural stability of the robust UiO-66 in wastewater treatment processes, making it suitable for a large scale application.

DOI

10.1016/j.jcis.2017.04.001

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