Melamine foam derived nitrogen and boron co-doped metal-free electrode for enhanced electro-fenton degradation of metronidazole
Chemical Engineering Journal
School of Engineering
National Science and Technology Major Project (Grant No. 2016ZX05040003) / Applied Research Project of Qingdao postdoctoral Researchers (qdyy20210090)
In this work, a melamine foam derived nitrogen (N) and boron (B) co-doped metal-free electrode was prepared by accessible method and applied in heterogeneous electro-Fenton (EF) system. Overcoming the metal ion leaching and harsh operating conditions of most transition metal electrodes, the prepared metal-free electrode (NB/CF40) possessed an excellent EF performance for degradation of metronidazole (MTZ) in a wide range of pH (3 – 11), maintaining great reusability even after ten runs with higher mineralized current efficiency (MCE) and lower energy consumption (EC). Significantly, the NB/CF40 has excellent decontamination performance for actual wastewater containing MTZ analyzed by quadrupole time-of-flight mass spectrometry (UPLC-Q-TOF-MS) and three-dimensional excitation-emission matrix fluorescence spectra (3D EEMs). According to experimental results, characterization analysis and density functional theory (DFT) calculations, EF reaction mechanism by NB/CF40 cathode was proposed, in which the active sites of B – C – C – C-graphitic N and B – C – C – C-pyridinic N configurations contributed to the improvement of EF performance by affecting the charge density of nearby carbon framework, adsorption of O2, and desorption of *OOH. This work offers a new idea for the remediation of wastewater by the efficient metal-free EF system in a wide pH range.
Zhao, H., Ma, X., Lu, M., He, F., Lin, F., Zhang, Y., ... & Sun, H. (2023). Melamine foam derived nitrogen and boron co-doped metal-free electrode for enhanced electro-fenton degradation of metronidazole. Chemical Engineering Journal, 455, Article 140593. https://doi.org/10.1016/j.cej.2022.140593