Document Type

Journal Article

Publisher

MDPI

School

School of Engineering

Comments

Originally published as: Li, Y., Li, D., Han, W., Zhang, M., Ai, B., Zhang, L., ... Cui, Z. (2019). Facile synthesis of di-mannitol adipate ester-based zinc metal alkoxide as a bi-functional additive for poly(vinyl chloride). Polymers, 11(5), Article 813. Original publication available here

Abstract

A new di-mannitol adipate ester-based zinc metal alkoxide (DMAE-Zn) was synthesized as a bi-functional poly(vinyl chloride) (PVC) thermal stabilizer for the first time. The materials were characterized with Fourier transform infrared spectroscopy (FT-IR) and thermogravimetric analysis (TGA). Characterization results confirmed the formation of Zn–O bonds in DMAE-Zn, and confirmed that DMAE-Zn had a high decomposition temperature and a low melting point. The thermal stability of DMAE-Zn on PVC also was tested by a conductivity test, a thermal aging test, and a UV-visible spectroscopy (UV-VIS) test. PVC stabilized by DMAE-Zn had a good initial color and excellent long-term stability. UV-VIS also showed that the conjugated structure in PVC stabilized by DMAE-Zn was almost all of the triene, suggesting that the addition of DMAE-Zn would suppress the formation of conjugated structures above tetraene. The dynamic processing performance of PVC samples tested by torque rheometer indicated that, having a good compatibility with PVC chains in the amorphous regions, DMAE-Zn contributed a good plasticizing effect to PVC. DMAE-Zn thus effectively demonstrates bi-functional roles, e.g., thermal stabilizers and plasticizers to PVC. Furthermore, FT-IR, a HCl absorption capacity test, and a complex ZnCl2 test were also used to verify the thermal stability mechanism of DMAE-Zn for PVC.

DOI

10.3390/polym11050813

Creative Commons License

Creative Commons Attribution 4.0 License
This work is licensed under a Creative Commons Attribution 4.0 License.

Included in

Engineering Commons

Share

 
COinS