Document Type

Journal Article

Publication Title

Polymers

Publisher

MDPI

School

School of Engineering

RAS ID

30562

Comments

Li, Y., Li, D., Han, W., Zhang, M., Ai, B., Zhang, L., ... Cui, Z. (2019). Facile synthesis of di-mannitol adipate ester-based zinc metal alkoxide as a bi-functional additive for poly(vinyl chloride). Polymers, 11(5), Article 813. Available here

Abstract

A new di-mannitol adipate ester-based zinc metal alkoxide (DMAE-Zn) was synthesized as a bi-functional poly(vinyl chloride) (PVC) thermal stabilizer for the first time. The materials were characterized with Fourier transform infrared spectroscopy (FT-IR) and thermogravimetric analysis (TGA). Characterization results confirmed the formation of Zn–O bonds in DMAE-Zn, and confirmed that DMAE-Zn had a high decomposition temperature and a low melting point. The thermal stability of DMAE-Zn on PVC also was tested by a conductivity test, a thermal aging test, and a UV-visible spectroscopy (UV-VIS) test. PVC stabilized by DMAE-Zn had a good initial color and excellent long-term stability. UV-VIS also showed that the conjugated structure in PVC stabilized by DMAE-Zn was almost all of the triene, suggesting that the addition of DMAE-Zn would suppress the formation of conjugated structures above tetraene. The dynamic processing performance of PVC samples tested by torque rheometer indicated that, having a good compatibility with PVC chains in the amorphous regions, DMAE-Zn contributed a good plasticizing effect to PVC. DMAE-Zn thus effectively demonstrates bi-functional roles, e.g., thermal stabilizers and plasticizers to PVC. Furthermore, FT-IR, a HCl absorption capacity test, and a complex ZnCl2 test were also used to verify the thermal stability mechanism of DMAE-Zn for PVC.

DOI

10.3390/polym11050813

Creative Commons License

Creative Commons Attribution 4.0 License
This work is licensed under a Creative Commons Attribution 4.0 License.

Research Themes

Natural and Built Environments

Priority Areas

Engineering, technology and nanotechnology

Included in

Engineering Commons

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