Tailoring the separation selectivity of metal complexes and organometallic compounds resolved by capillary electrophoresis using auxiliary separation processes

Authors

Mary Boyce, Edith Cowan UniversityFollow
Paul Haddad

Document Type

Journal Article

Keywords

Ion-exchange electrokinetic capillary chromatography, Ion-pairing, Metal complex, Micellar electrokinetic capillary chromatography, Review, Separation selectivity

Publisher

Wiley - VCH Verlag

Faculty

Faculty of Computing, Health and Science

School

School of Natural Sciences

RAS ID

1945

Comments

Boyce, M. C., & Haddad, P. R. (2003). Tailoring the separation selectivity of metal complexes and organometallic compounds resolved by capillary electrophoresis using auxiliary separation processes. Electrophoresis, 24(12‐13), 2013-2022. Available here

Abstract

The use of auxiliary separation mechanisms to manipulate the separation selectivity of metal complexes and organometallic species is reviewed. Auxiliary separation mechanisms included in the review are micellar electrokinetic capillary chromatography, ion-pairing and ion-exchange electrokinetic chromatography. This paper discusses how these secondary mechanisms can be effectively employed to tailor separation selectivity.