Document Type

Journal Article

Publication Title

Molecules

Volume

27

Issue

1

Publisher

MDPI

School

School of Medical and Health Sciences

RAS ID

51986

Funders

Curtin Research Fellowship

Raine Medical Research Foundation

Dementia Australia Research Foundation

Comments

Ioppolo, A., Eccles, M., Groth, D., Verdile, G., & Agostino, M. (2022). Evaluation of virtual screening strategies for the identification of γ-secretase inhibitors and modulators. Molecules, 27(1), article 176.

https://doi.org/10.3390/molecules27010176

Abstract

γ-Secretase is an intramembrane aspartyl protease that is important in regulating normal cell physiology via cleavage of over 100 transmembrane proteins, including Amyloid Precursor Protein (APP) and Notch family receptors. However, aberrant proteolysis of substrates has implications in the progression of disease pathologies, including Alzheimer’s disease (AD), cancers, and skin disorders. While several γ-secretase inhibitors have been identified, there has been toxicity observed in clinical trials associated with non-selective enzyme inhibition. To address this, γ-secretase modulators have been identified and pursued as more selective agents. Recent structural evidence has provided an insight into how γ-secretase inhibitors and modulators are recognized by γ-secretase, providing a platform for rational drug design targeting this protease. In this study, docking-and pharmacophore-based screening approaches were evaluated for their ability to identify, from libraries of known inhibitors and modulators with decoys with similar physicochemical properties, γ-secretase inhibitors and modulators. Using these libraries, we defined strategies for identifying both γ-secretase inhibitors and modulators incorporating an initial pharmacophore-based screen followed by a docking-based screen, with each strategy employing distinct γ-secretase structures. Furthermore, known γ-secretase inhibitors and modulators were able to be identified from an external set of bioactive molecules following application of the derived screening strategies. The approaches described herein will inform the discovery of novel small molecules targeting γ-secretase.

DOI

10.3390/molecules27010176

Creative Commons License

Creative Commons Attribution 4.0 License
This work is licensed under a Creative Commons Attribution 4.0 License.

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