Abstract

A novel one-step method to prepare the nanocomposites of reduced graphene oxide (RGO)/nanoporous gold (NPG) is realized by chemically dealloying an Al2Au precursor. The RGO nanosheets anchored on the surface of NPG have a cicada wing like shape and act as both conductive agent and buffer layer to improve the catalytic ability of NPG for methanol electro-oxidation reaction (MOR). This improvement can also be ascribed to the microstructure change of NPG in dealloying with RGO. This work inspires a facile and economic method to prepare the NPG based catalyst for MOR.

Keywords

Aluminum alloys, Buffer layers, Catalytic oxidation, Dealloying, Electrooxidation, Gold, Gold alloys, Graphene, Methanol, Catalytic ability, Graphene sheets, High activity, Methanol electrooxidation, Microstructure changes, One-step methods, Porous gold, Reduced graphene oxides (RGO), Catalyst activity

Document Type

Journal Article

Date of Publication

1-1-2020

Publication Title

RSC Advances

Publisher

Royal Society of Chemistry

School

School of Engineering

RAS ID

30902

Funders

Funding information available at: https://doi.org/10.1039/C9RA09821F

Creative Commons License

Creative Commons Attribution 3.0 License
This work is licensed under a Creative Commons Attribution 3.0 License.

Comments

Xu, H., Liu, S., Pu, X., Shen, K., Zhang, L., Wang, X., ... & Wang, W. (2020). Dealloyed porous gold anchored by in situ generated graphene sheets as high activity catalyst for methanol electro-oxidation reaction. RSC Advances, 10(3), 1666-1678. https://doi.org/10.1039/c9ra09821f

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Engineering Commons

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Link to publisher version (DOI)

10.1039/c9ra09821f